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Updated: Jun 8, 2026

Synthesis of Terpolymers at Mild Temperatures Using Dynamic Sulfur Bonds in Poly(S-Divinylbenzene)
Published on: May 20, 2019
Modification of polydivinylbenzene microspheres by a hydrobromination/click-chemistry protocol and their
Yasemin Yuksel Durmaz1, Bunyamin Karagoz, Niyazi Bicak
1Istanbul Technical University, Faculty of Science and Letters, Department of Chemistry, Maslak 34469 Istanbul, Turkey.
Abstract:
Hydrophobic- and/or hydrophilic-polymer-grafted PDVB microspheres are synthesized by the combination of hydrobromination and click-chemistry processes. The modified-PDVB microspheres and the intermediates at various stages of synthesis are characterized using GPC, ¹H NMR and FTIR spectroscopy and TGA analysis. Use of the microspheres as a support matrix for reversible protein immobilization via adsorption is investigated. The system parameters such as the adsorption conditions (i.e., enzyme concentration, medium pH) and desorption are studied and evaluated with regards to the biocatalytic activity and adsorption capacity.

