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A Technical Guide for Performing Spectroscopic Measurements on Metal-Organic Frameworks
Published on: April 28, 2023
Assessing the purity of metal-organic frameworks using photoluminescence: MOF-5, ZnO quantum dots, and framework
Patrick L Feng1, John J Perry, Stefan Nikodemski
1Sandia National Laboratories, Livermore, California 94551-0969, USA.
Journal of the American Chemical Society
|October 22, 2010
Abstract:
Photoluminescence (PL) spectroscopy was used to characterize nanoscale ZnO impurities, amine-donor charge-transfer exciplexes, and framework decomposition in samples of MOF-5 prepared by various methods. The combined results cast doubt on previous reports describing MOF-5 as a semiconductor and demonstrate that PL as a tool for characterizing MOF purity possesses advantages such as simplicity, speed, and sensitivity over currently employed powder XRD MOF characterization methods.
