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Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks
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A generic approach for preparing core-shell carbon-metal oxide nanofibers: morphological evolution and its mechanism

Junhua Kong1, Hui Ru Tan, Sze Yu Tan

  • 1School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798.

Chemical Communications (Cambridge, England)
|October 22, 2010
PubMed

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The mechanism for anionic chain-growth polymerization involves initiation, propagation, and termination steps. In the initiation step, a nucleophilic anion, such as butyl lithium, initiates the polymerization process by attacking the π bond of the vinylic monomer. As a result, a carbanion, stabilized by the electron‐withdrawing group, is generated. The resulting carbanion acts as a Michael donor in the propagation step and attacks the second vinylic monomer, which acts as a Michael acceptor.