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Updated: Jun 7, 2026

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
Chiral gels derived from secondary ammonium salts of (1R,3S)-(+)-camphoric acid
Tapas Kumar Adalder1, N N Adarsh, Ravish Sankolli
1Indian Association for the Cultivation of Science, Kolkata, India. tka.chem@yahoo.com
Abstract:
In order to have access to chiral gels, a series of salts derived from (1R,3S)-(+)-camphoric acid and various secondary amines were prepared based on supramolecular synthon rationale. Out of seven salts prepared, two showed moderate gelation abilities. The gels were characterized by differential scanning calorimetry, table top rheology, scanning electron microscopy, single crystal and powder X-ray diffraction. Structure property correlation based on X-ray diffraction techniques remain inconclusive indicating that some of the integrated part associated with the gelation phenomena requires a better understanding.
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