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The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
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Alkyne-stabilized ruthenium nanoparticles: manipulation of intraparticle charge delocalization by nanoparticle charge

Xiongwu Kang1, Nathaniel B Zuckerman, Joseph P Konopelski

  • 1Department of Chemistry and Biochemistry, University of California, 1156 High Street, Santa Cruz, CA 95064, USA.

Angewandte Chemie (International Ed. in English)
|October 30, 2010
PubMed
Abstract

No abstract available in PubMed .

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The presence of electron-donating, electron-withdrawing, or conjugating groups adjacent to a radical center, imparts electronic stabilization to the radicals. Examples of such electronically-stabilized radicals are triphenylmethyl, tetramethylpiperidine‐N‐oxide, and 2,2‐diphenyl‐1‐picrylhydrazyl. These radicals are remarkably stable and are known as persistent radicals. Some of the persistent radicals can even be isolated and purified.
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