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Synthesis and Characterization of Supramolecular Colloids
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Organosilica spheres covalently functionalized with diphenylanthracene and viologen units

Mercedes Álvaro1, Giorgia Bizzoca, Belén Ferrer

  • 1Instituto de Tecnología Química CSIC-UPV and Departamento de Quimica, Universidad Politécnica de Valencia, Camino de Vera s/n, 46022 Valencia, Spain.

Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry
|October 30, 2010
PubMed

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Conjugated dienes are compounds characterized by the presence of alternating double and single bonds. In a conjugated system like 1,3-butadiene, the unhybridized 2p orbital on each carbon overlaps continuously, allowing the π electrons to be delocalized across the entire molecule. In contrast, this type of overlap does not occur in cumulated and isolated dienes, such as 2,3-pentadiene and 1,4-pentadiene, respectively. Instead, the π electrons remain localized between the double...