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Related Concept Videos

Flame Photometry: Lab01:16

Flame Photometry: Lab

In a flame photometer, when a solution like potassium chloride is aspirated into the flame, the solvent evaporates, leaving behind dehydrated salt. This salt dissociates into free gaseous atoms in their ground state. Some of these atoms absorb energy from the flame, leading to their excitation. The excited atoms return to the ground state, emitting photons at characteristic wavelengths. Because only electronic transitions are involved, the resulting emission lines are very narrow. The intensity...
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Flame photometry, also known as flame emission spectrometry, is a technique used for the qualitative and quantitative analysis of elements present in a sample using a flame as the source of excitation energy. The concept of flame photometry was realized in the early 1860s by Kirchhoff and Bunsen, who discovered that specific elements emit characteristic radiation when excited in flames. The first instrument developed for this purpose was used to measure sodium (Na) in plant ash using a Bunsen...
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Electrochemistry is the branch of chemistry that studies the relationship between electrical quantities and chemical reactions, particularly oxidation and reduction. Oxidation is the loss of electrons from a substance, whereas reduction refers to the gain of electrons. A substance with a strong electron affinity is called an oxidizing agent (oxidant), and a reducing agent (reductant) is a species that donates electrons. Oxidation and reduction processes are pivotal to electrochemical reactions,...
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In atomic emission spectroscopy (AES), high-temperature atomizers excite a broad range of elements and molecules that generate complex emissions from sources such as oxides, hydroxides, and flame combustion products in the flame or plasma. Several strategies can be employed to minimize spectral interferences caused by overlapping emission lines or bands. These include increasing instrument resolution, choosing alternative emission lines, optimally placing the detector in low-background regions,...
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In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
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Electrochemical systems provide a fascinating insight into the dynamic interplay of charged species within various phases. One notable example is the interaction between a membrane permeable to K⁺ ions but not to Cl⁻ ions, separating an aqueous KCl solution from pure water. As K⁺ ions diffuse through the membrane, they generate net charges on each phase, leading to a potential difference between them.Similarly, when a piece of Zn is immersed in an aqueous ZnSO₄ solution, the Zn metal, composed...

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Combustion Chemistry of Fuels: Quantitative Speciation Data Obtained from an Atmospheric High-temperature Flow Reactor with Coupled Molecular-beam Mass Spectrometer
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Combustion Chemistry of Fuels: Quantitative Speciation Data Obtained from an Atmospheric High-temperature Flow Reactor with Coupled Molecular-beam Mass Spectrometer

Published on: February 19, 2018

Electrochemistry in flames.

Dimitris Sarantaridis1, Toks Fowowe, Daren J Caruana

  • 1Electrochemistry Laboratory, Department of Chemistry, University College London.

Science Progress
|November 5, 2010
PubMed
Summary
This summary is machine-generated.

This paper explores the lesser-known electrochemical properties of flames, revealing their plasma nature. These conductive properties enable the development of novel flame electrochemical systems, similar to batteries.

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Area of Science:

  • Combustion Science
  • Electrochemistry
  • Plasma Physics

Background:

  • Flames and combustion are foundational to engineering and chemistry.
  • The electrochemical properties of flames are less understood than their thermal aspects.

Purpose of the Study:

  • To highlight the electrochemical properties of flames.
  • To discuss the plasma nature of flames and their conductive characteristics.
  • To explore the potential of flame electrochemical systems.

Main Methods:

  • Historical review of flame studies.
  • General discussion on flame formation and properties.
  • Analysis of charged species within flames.

Main Results:

  • Flames contain charged species, exhibiting plasma characteristics.
  • Flames behave as conductive media.
  • Flame electrochemical systems can generate voltages.

Conclusions:

  • The plasma properties of flames offer significant research potential.
  • Flames can be integrated with existing electrochemical methodologies.
  • New avenues in electrochemical research can be opened using flame properties.