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Synthesis and Characterization of Functionalized Metal-organic Frameworks
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Synthesis and Characterization of Functionalized Metal-organic Frameworks

Published on: September 5, 2014

Photochemical activation of a metal-organic framework to reveal functionality

Kristine K Tanabe1, Corinne A Allen, Seth M Cohen

  • 1Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive, La Jolla, CA 92093, USA.

Angewandte Chemie (International Ed. in English)
|November 11, 2010
PubMed
Abstract

No abstract available in PubMed .

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Some cycloaddition reactions are activated by heat, while others are initiated by light. For example, a [2 + 2] cycloaddition between two ethylene molecules occurs only in the presence of light. It is photochemically allowed but thermally forbidden.