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Sulfur versus iron oxidation in an iron-thiolate model complex

Aidan R McDonald1, Michael R Bukowski, Erik R Farquhar

  • 1Department of Chemistry and Center for Metals in Biocatalysis, 207 Pleasant Street SE, University of Minnesota, Minneapolis, Minnesota 55455, USA.

Journal of the American Chemical Society
|November 13, 2010
PubMed
Summary

This study reveals a new sulfur oxidation pathway for iron complexes. Without base, peracid reacts with an iron(II) complex to form an iron(II)-sulfinate species, then an oxoiron(IV) complex with a sulfinate ligand.

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