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Related Concept Videos

Spectrophotometry: Introduction01:16

Spectrophotometry: Introduction

Spectrophotometry is the quantitative measurement of the absorption, reflection, diffraction, or transmission of electromagnetic radiation through a material as a function of the intensity and wavelength of the radiation. A spectrophotometer is a device used to measure the change in the radiation intensity caused by its interaction with the material.
The essential components of a spectrophotometer include a source of electromagnetic radiation, a slot for placing a material to be analyzed, and a...
Atomic Emission Spectroscopy: Overview01:20

Atomic Emission Spectroscopy: Overview

Atomic emission spectroscopy (AES) is an analytical technique used to determine the elemental composition of a sample by analyzing the light emitted from excited atoms. In AES, atoms in a sample are excited to higher energy levels by thermal energy from high-temperature sources, such as plasma, arcs, or sparks. When these excited atoms return to lower energy states, they emit light at specific wavelengths characteristic of each element. The resulting atomic emission spectrum, which consists of...
Inductively Coupled Plasma Atomic Emission Spectroscopy: Instrumentation01:26

Inductively Coupled Plasma Atomic Emission Spectroscopy: Instrumentation

Inductively coupled plasma (ICP) is the common plasma source used in atomic emission spectroscopy (AES), a technique that detects and analyzes various elements in a sample. This method is often called inductively coupled plasma atomic emission spectroscopy (ICP-AES).
There are three main types of inductively coupled plasma atomic emission spectroscopy  (ICP-AES) instruments: sequential, simultaneous multichannel, and Fourier transform instruments, with the latter being less commonly used.
Atomic Emission Spectroscopy: Interference01:30

Atomic Emission Spectroscopy: Interference

In atomic emission spectroscopy (AES), high-temperature atomizers excite a broad range of elements and molecules that generate complex emissions from sources such as oxides, hydroxides, and flame combustion products in the flame or plasma. Several strategies can be employed to minimize spectral interferences caused by overlapping emission lines or bands. These include increasing instrument resolution, choosing alternative emission lines, optimally placing the detector in low-background regions,...
Atomic Absorption Spectroscopy: Interference01:25

Atomic Absorption Spectroscopy: Interference

Interference leads to systematic error in atomic absorption (AA) measurements by enhancing or diminishing the analytical signal or the background. These interferences can be grouped into three main categories: spectral interference, chemical interference, and physical interference.
Spectral interference occurs when signals from other elements or molecules overlap with the analyte signal, falsely elevating or masking the analyte's absorbance. This interference can be corrected using Zeeman,...
Atomic Emission Spectroscopy: Instrumentation01:22

Atomic Emission Spectroscopy: Instrumentation

The instrumentation of atomic emission spectrometry (AES) involves various components, including atomization devices that convert samples into gas-phase atoms and ions. There are two main types of atomization devices: continuous and discrete atomizers.  Continuous atomizers, like plasmas and flames, introduce samples in a constant stream, while discrete atomizers inject individual samples using syringes or autosamplers. The most common discrete atomizer is the electrothermal atomizer.

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Related Experiment Video

Updated: Jun 6, 2026

Composition and Distribution Analysis of Bioaerosols Under Different Environmental Conditions
05:45

Composition and Distribution Analysis of Bioaerosols Under Different Environmental Conditions

Published on: January 7, 2019

Spectral attenuation and aerosol particle size distribution.

K S Shifrin, I G Zolotov

    Applied Optics
    |November 19, 2010
    PubMed
    Summary

    This study presents a numerical method for reconstructing particle size distributions from spectral attenuation data. The approach uses regularization and an objective validity estimate, successfully applied to marine aerosols.

    Area of Science:

    • Atmospheric Science
    • Optical Physics
    • Numerical Analysis

    Background:

    • Accurate particle size distribution (PSD) is crucial for understanding aerosol properties and their impact on climate and visibility.
    • Reconstructing PSD from spectral attenuation data presents an inverse problem, often ill-posed and sensitive to noise.
    • Existing methods may lack robust parameter selection or applicability to complex aerosol systems like marine aerosols.

    Purpose of the Study:

    • To develop and validate a numerical algorithm for reconstructing particle size distribution (PSD) from spectral attenuation data.
    • To introduce a method for selecting the regularization parameter based on an objective validity estimate.
    • To assess the applicability and accuracy of the proposed method for marine aerosol PSD reconstruction.

    Main Methods:

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    • The study employs a regularization technique to solve the inverse problem of PSD reconstruction.
    • A novel method for choosing the regularization parameter is proposed, based on objective validity estimation of the solution.
    • Numerical experiments are conducted to test the algorithm's performance and estimate accuracy within specific radius intervals.

    Main Results:

    • The numerical algorithm demonstrates applicability to reconstructing the PSD of marine aerosols.
    • An objective method for selecting the regularization parameter improves the reliability of the reconstructed PSD.
    • The study estimates the achievable accuracy of the distribution function within a defined radius interval, considering factors like spectral range and data point distribution.

    Conclusions:

    • The regularization-based numerical method is effective for reconstructing particle size distributions from spectral attenuation data.
    • The proposed objective validity estimation provides a reliable approach for parameter selection in inverse problems.
    • The method's performance is validated for marine aerosols, with insights into extending the applicable radius interval through extrapolation.