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Preparation of p-type CaFe2O4 photocathodes for producing hydrogen from water
Shintaro Ida1, Keisuke Yamada, Takuya Matsunaga
1Department of Applied Chemistry, Faculty of Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan. s-ida@cstf.kyushu-u.ac.jp
Abstract:
An (hk0)-oriented p-type CaFe2O4 (E(g): 1.9 eV) photocathode was prepared, and hydrogen and oxygen gases were produced from a photocell short-circuited by connecting the CaFe2O4 and n-type TiO2 electrodes under illumination without applying an external voltage. The open-circuited voltage was 0.97 V and the short-circuit current was about 200 μA/cm(2), and the amount of evaluated hydrogen and oxygen gases after 2 days of reaction were about 70 and 4 μmol, respectively.

