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Updated: Jun 6, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
High heat of hydrogen adsorption and guest-responsive magnetic modulation in a 3D porous pillared-layer coordination
Arpan Hazra1, Prakash Kanoo, Tapas Kumar Maji
1Molecular Materials Laboratory, Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore 560 064, India.
Abstract:
A bimetallic pillared-layer coordination framework {[Mn(3)(bipy)(3)(H(2)O)(4)][Cr(CN)(6)](2)·2(bipy)·4(H(2)O)}(n) has been constructed using a cyanometallate anion ([Cr(CN)(6)](3-)) and an organic linker (4,4'-bipyridyl) that provides high heat of hydrogen adsorption (∼11.5 kJ mol(-1)) and shows guest dependent magnetic modulation.
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