Related Experiment Video
Updated: Jun 6, 2026

Non-equilibrium Microwave Plasma for Efficient High Temperature Chemistry
Published on: August 1, 2017
[Study on vibrational temperature and gas temperature in a hollowneedle-plate discharge plasma]
Li-fang Dong1, Wei-yuan Liu, Yu-jie Yang
1College of Physics Science and Technology, Hebei University, Baoding 071002, China. donglf@mail.hbu.edu.cn
Abstract:
A 1.6-3 cm long plasma torch was generated when argon gas was introduced by using a hollowneedle-plate discharge device working in atmosphere. The vibrational temperature and the gas temperature at plasma root and tip were studied by using optical emission spectrum at different argon gas flow. The gas temperature was obtained by comparing experimental line shape of OH radicals band around 309 nm with its simulated line shape. The vibrational temperature was calculated using N2 second posi tive band system C3:pi u-B3 pi g. It was found that the gas temperatures at arc root and arc tip are equal and they decrease with the argon flow rate increasing. The gas temperature decreases from 350 to 300 K when argon flow rate increases from 3.0 to 6.5 mL x min(-1). The vibrational temperature at are tip (1950 K) is higher than that at arc root (1755 K) under a low gas flow rate (e.g., 3.0 mL x min(-1)). With gas flow rate increasing, the vibrational temperature at both tip and root decreases, but the decreasing rate at are tip is faster than that at arc root. When gas flow is larger, the vibrational temperatures at tip and root tend to be equal.
Related Concept Videos
Atomic Spectroscopy: Effects of Temperature
At thermal equilibrium, the relative populations of excited and ground state atoms can be estimated using the Maxwell–Boltzmann distribution. For example, an increase in temperature from...
Heat Capacities of an Ideal Gas III
Gas Thermometers and the Kelvin Scale
Heat Capacities of an Ideal Gas II
Column Efficiency: Plate Theory
A higher number of theoretical plates signifies better column efficiency and improved separation capabilities. Plate height affects bandwidth and separation quality; it is inversely...
Temperature and Thermal Equilibrium
The concept of temperature has evolved from the common concepts of hot and cold. The scientific definition of temperature explains more than just our sense of hot and cold. Temperature is operationally defined as the quantity measured with a thermometer. Furthermore, temperature is...

