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IR Frequency Region: X–H Stretching

IR Frequency Region: X–H Stretching

In IR spectroscopy, signals produced by the X−H bonds (such as C−H, O−H, or N−H) can be observed in the frequency range of 2700–4000 cm–1. The C−H stretching vibration forms sharp bands in the region 2850–3000 cm–1. The presence of the O−H stretching vibration leads to the forming of an absorption band in the frequency range 3650–3200 cm−1. At the same time, N−H stretching can be confirmed by absorption bands in the 3500–3100 cm−1 range. Even though both O−H and N−H bonds vibrate at a similar...

IR Spectrometers

IR Spectrometers

There are two main infrared (IR) spectrophotometers: dispersive IR spectrometers and Fourier transform infrared (FTIR) spectrometers. In a dispersive IR spectrometer, a beam of infrared radiation produced by a hot wire is divided into two parallel equal-intensity beams using mirrors. One beam passes through the sample, while another is a reference beam. The beams then move through the monochromator, which separates the radiations into a continuous spectrum of different frequencies. The...

IR Frequency Region: Fingerprint Region

IR Frequency Region: Fingerprint Region

IR spectra are divided into two main regions: the diagnostic region and the fingerprint region. The diagnostic region of the spectrum lies above 1500 cm−1. The absorptions resulting from single-bond vibrations of the N–H, C–H, and O–H stretch at higher wavenumbers and appear on the left side of the spectrum. The stretching absorptions of the C≡C and C≡N occur between 2100–2300 cm−1. In contrast, those arising from stretching absorptions of the C=O, C=N, and C=C occur between 1600–1850 cm−1.
The...

IR Spectrum

IR Spectrum

When infrared (IR) radiation passes through a molecule, the bonds stretch or bend by absorbing the radiation. This absorption creates the molecule's absorption spectrum, which is the plot of its percentage transmittance versus wavenumber.
Transmittance is defined as the ratio of the radiant power passing through a sample to that from the radiation's source. Multiplying the transmittance by 100 gives the percent transmittance (%T), which varies between 100% (no absorption) and 0% (complete...

Infrared (IR) Spectroscopy: Overview

Infrared (IR) Spectroscopy: Overview

When electromagnetic radiation passes through a material, atoms or molecules transition from a lower to a higher energy state by absorbing radiation corresponding to the energy difference between the two states. The absorption of infrared (IR) radiation causes transitions between vibrational energy levels in a molecule. Therefore, IR spectroscopy is a useful analytical tool for determining the molecular structure of molecules.
Different compounds display unique properties due to their...

IR Spectrum Peak Splitting: Symmetric vs Asymmetric Vibrations

IR Spectrum Peak Splitting: Symmetric vs Asymmetric Vibrations

Identical bonds within a polyatomic group can stretch symmetrically (in-phase) or asymmetrically (out-of-phase). Similar to hydrogen bonding, these vibrations also influence the shape of the IR peak. Generally, asymmetric stretching frequencies are higher than symmetric stretching frequencies. For example, primary amines exhibit two distinct IR peaks between 3300–3500 cm−1 corresponding to the symmetric and asymmetric N-H stretching, while secondary amines exhibit a single stretching vibration...

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Related Experiment Video

Updated: Jun 6, 2026

Infrared Degenerate Four-wave Mixing with Upconversion Detection for Quantitative Gas Sensing

Infrared Degenerate Four-wave Mixing with Upconversion Detection for Quantitative Gas Sensing

Published on: March 22, 2019

Bandwidth extension for IR detectors through spatial-frequency shifting.

A H Lettington, Q H Hong, S Tzimopoulou

|December 4, 2010

Summary

This study introduces a novel reticle method to enhance infrared (IR) detector bandwidth. The technique enables high-resolution imaging by capturing and reconstructing spatial-frequency information.

Area of Science:

Optics and Photonics
Infrared Technology
Image Processing

Background:

Infrared (IR) detectors have limited bandwidth, restricting their ability to capture high-resolution images.
High spatial frequencies in a scene contain crucial details for image resolution.

Purpose of the Study:

To propose a new method for extending the effective bandwidth of IR detector systems.
To enable the reconstruction of high-resolution images from IR detector data.

Main Methods:

A reticle is employed to shift high spatial frequencies to a lower-frequency region.
The reticle modifies the scene's spatial-frequency content to match the detector's bandwidth.
Image reconstruction is performed from multiple images captured at predetermined reticle positions.

More Related Videos

Wideband Optical Detector of Ultrasound for Medical Imaging Applications

Wideband Optical Detector of Ultrasound for Medical Imaging Applications

Published on: May 11, 2014

A Multimodal Wide-Field Fourier-Transform Raman Microscope

A Multimodal Wide-Field Fourier-Transform Raman Microscope

Published on: December 30, 2025

Related Experiment Videos

Last Updated: Jun 6, 2026

Infrared Degenerate Four-wave Mixing with Upconversion Detection for Quantitative Gas Sensing

Infrared Degenerate Four-wave Mixing with Upconversion Detection for Quantitative Gas Sensing

Published on: March 22, 2019

Wideband Optical Detector of Ultrasound for Medical Imaging Applications

Wideband Optical Detector of Ultrasound for Medical Imaging Applications

Published on: May 11, 2014

A Multimodal Wide-Field Fourier-Transform Raman Microscope

A Multimodal Wide-Field Fourier-Transform Raman Microscope

Published on: December 30, 2025

Main Results:

The proposed reticle scheme allows all spatial-frequency information to pass through the detector system's bandwidth.
This method facilitates the capture of information typically lost due to bandwidth limitations.
High-resolution image reconstruction is demonstrated through a series of captured images.

Conclusions:

The reticle-based approach effectively extends the bandwidth of IR detectors.
This technique offers a viable solution for achieving high-resolution imaging with existing IR detector systems.
The method provides a pathway for enhanced detail retrieval in infrared imaging applications.