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Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
From metal-organic squares to porous zeolite-like supramolecular assemblies
Shuang Wang1, Tingting Zhao, Guanghua Li
1State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China.
Journal of the American Chemical Society
|December 8, 2010
Abstract:
We report the synthesis, structure, and characterization of two novel porous zeolite-like supramolecular assemblies, ZSA-1 and ZSA-2, having zeolite gis and rho topologies, respectively. The two compounds were assembled from functional metal-organic squares (MOSs) via directional hydrogen-bonding interactions and exhibited permanent microporosity and thermal stability up to 300 °C.
