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Updated: Jun 6, 2026
A Polyaniline-based Sensor of Nucleic Acids
Published on: November 1, 2016
Changes in electronic properties of polymeric one-dimensional {[M(CN)2]-}n (M = Au, Ag) chains due to neighboring
François Baril-Robert1, Xiaobo Li, Michael J Katz
1Department of Chemistry, University of Maine, Orono, Maine 04473, USA.
Abstract:
A series of d(10) dicyanometallate polymeric compounds were studied by electronic spectroscopy and density functional theory (DFT) calculations. In these materials, the negatively charged one-dimensional (1D) polymeric chains are linked together by [M(en)(2)](2+) (M = Cu(II) and Zn(II); en = ethylenediamine). More than innocent building blocks, the [M(en)(2)](2+) units offer a possible synthetic way to modify electronic properties of the materials. Through its low energy d-d excited state, the d(9) copper(II) ions offer deactivation pathways for the normally emissive dicyanometallate polymer. Deactivation was shown to be specific to the excited state energy.
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