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Updated: Jun 6, 2026
Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
Published on: April 9, 2018
Molecular conductors with a 8-hydroxy cobalt bis(dicarbollide) anion
Olga N Kazheva1, Grigorii G Alexandrov, Andrey V Kravchenko
1Institute of Problems of Chemical Physics, Russian Academy of Sciences, Semenov Av. 1, 142432 Chernogolovka, Moscow Region, Russia.
Abstract:
Molecular conductors based on the 8-hydroxy cobalt bis(dicarbollide) anion, (TMTTF)[8-HO-3,3'-Co(1,2-C2B9H10)(1',2'-C2B9H11)] (1), (BMDT-TTF)[8-HO-3,3'-Co(1,2-C2B9H10) (1',2'-C2B9H11)] (2), and (BEDT-TTF)[8-HO-3,3'-Co(1,2-C2B9H10)(1',2'-C2B9H11)] (3), were synthesized, and their crystal structures and electrical conductivities were determined. Compounds 2 and 3 are isostructural to the corresponding radical-cation salts of the parent cobalt bis(dicarbollide). All of the radical-cation salts prepared were found to be semiconductors. The relative stability of the rotation conformers of the [8-HO-3,3'-Co(1,2-C2B9H10)(1',2'-C2B9H11)](-) anion was estimated using DFT/BP86 quantum chemical calculations.
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