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Updated: Jun 5, 2026

Confocal Imaging of Confined Quiescent and Flowing Colloid-polymer Mixtures
Published on: May 20, 2014
Phase behavior of polydisperse spheres: simulation strategies and an application to the freezing transition
Nigel B Wilding1, Peter Sollich
1Department of Physics, University of Bath, Bath BA2 7AY, United Kingdom. n.b.wilding@bath.ac.uk
Abstract:
The statistical mechanics of phase transitions in dense systems of polydisperse particles presents distinctive challenges to computer simulation and analytical theory alike. The core difficulty, namely, dealing correctly with particle size fractionation between coexisting phases, is set out in the context of a critique of previous simulation work on such systems. Specialized Monte Carlo simulation techniques and moment free energy method calculations, capable of treating fractionation exactly, are then described and deployed to study the fluid-solid transition of an assembly of repulsive spherical particles described by a top-hat "parent" distribution of particle sizes. The cloud curve delineating the solid-fluid coexistence region is mapped as a function of the degree of polydispersity δ, and the properties of the incipient "shadow" phases are presented. The coexistence region is found to shift to higher densities as δ increases, but does not exhibit the sharp narrowing predicted by many theories and some simulations.
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