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Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
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A two-coordinate nickel imido complex that effects C−H amination

Carl A Laskowski1, Alexander J M Miller, Gregory L Hillhouse

  • 1Gordon Center for Integrative Science, Department of Chemistry, The University of Chicago, Chicago, Illinois 60637, United States.

Journal of the American Chemical Society
|December 24, 2010
PubMed
Summary

A novel nickel imido complex with a two-coordinate nickel center was synthesized. This complex exhibits a unique Ni═N bond and undergoes reactions like nitrene transfer and C−H insertion.

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