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A Synthetic Methodology for Preparing Impregnated and Grafted Amine-Based Silica Composites for Carbon Capture
Published on: September 29, 2023
Why hybrid porous solids capture greenhouse gases?
Gérard Férey1, Christian Serre, Thomas Devic
1Institut Lavoisier, CNRS 8180, Université de Versailles-St-Quentin, 45 Avenue des Etats-Unis, 78035 Versailles cedex, France. gferey@wanadoo.fr
Abstract:
Hybrid porous solids, with their tunable structures, their multifunctional properties and their numerous applications, are currently topical, particularly in the domain of adsorption and storage of greenhouse gases. Most of the data reported so far concern the performances of these solids in this domain, particularly in terms of adsorbed amounts of gas but do not explain at the atomic level why and how adsorption and storage occur. From a combination of structural, spectroscopic, thermodynamic experiments and of molecular simulations, this tutorial review proposes answers to these open questions with a special emphasis on CO(2) and CH(4) storage by some rigid and flexible hybrid porous materials.
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