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Updated: Jun 5, 2026

Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
Published on: June 9, 2023
Unusually large magnetic anisotropy in a CuO-based semiconductor Cu5V2O10
Zhangzhen He1, Chensheng Lin, Wendan Cheng
1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China. hcz1988@hotmail.com
Abstract:
A CuO-based material Cu(5)V(2)O(10) was successfully grown in a closed crucible using Sr(OH)(2)·8H(2)O as flux. The structure of Cu(5)V(2)O(10) can be viewed as being composed of two types of zigzag Cu-O chains running along the b- and c-axes, which shows a two-dimensional crosslike framework with 12-column square tunnels along the a-axis. Magnetic measurements show that Cu(5)V(2)O(10) exhibits unexpected large magnetic anisotropy, which is the first time magnetic anisotropy energy of ∼10(7) erg/cm(3) in the CuO-based materials has been observed. The origins of large anisotropy are suggested to arise from strong anisotropic exchanges due to the particular bonding geometry and the Jahn-Teller distortion of Cu(2+) ions. Further, the band structure investigated by the GGA+U method suggests that Cu(5)V(2)O(10) is a semiconductor.
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