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Preparation of SNS Cobalt(II) Pincer Model Complexes of Liver Alcohol Dehydrogenase
Published on: March 19, 2020
Diaqua-bis(2-carboxy-benzoato-κO)nickel(II)
Ya-Wen Xuan1, Wen Wu, Dong-Po Xie
1Department of Chemistry, Zhou Kou Normal University, Zhou Kou 466001, People's Republic of China.
Abstract:
In the title compound, [Ni(C(8)H(5)O(4))(2)(H(2)O)(2)], the Ni(II) atom lies on an inversion centre and exhibits a square-planar geometry incorporating two phthalate and two water O atoms. The nickel complex is stabilized by intra-molecular inter-actions involving water O atoms and H atoms of the phthalate groups. It forms one-dimensional zigzag chains along the b axis which are held together via π-π stacking inter-actions (3.647 Å) between the benzene rings of the phthalate groups. The adjacent chains are also hydrogen bonded, resulting in a three-dimensional supra-molecular network.
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