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Updated: Jun 5, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
Bis(isopropyl-ammonium) tetra-sulfido-molybdate(VI)
Abstract:
The title compound, (C(3)H(10)N)(2)[MoS(4)], was synthesized by passing a rapid stream of H(2)S into an aqueous isopropyl-amine solution of molybdic acid. The title compound is isotypic with the corresponding W analogue (C(3)H(10)N)(2)[WS(4)]; its structure consists of a slightly distorted tetra-hedral [MoS(4)](2-) dianion and two crystallographically independent isopropyl-ammonium cations, with all atoms located in general positions. The cations and anion are linked by weak N-H⋯S and C-H⋯S inter-actions, the strength and number of which can explain the observed Mo-S bond distances.
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