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Coordination Number and Geometry

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Amide Coupling Reaction for the Synthesis of Bispyridine-based Ligands and Their Complexation to Platinum as Dinuclear Anticancer Agents

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2,2',6,6'-Tetra-methyl-4,4'-bipyridine.

¹Department of Chemistry, TongHua Normal University, 134002, TongHua, Jilin, People's Republic of China.

Acta Crystallographica. Section E, Structure Reports Online

|January 5, 2011

Summary

The crystal structure of C(14)H(16)N(2) reveals a 19.48° dihedral angle between its pyridine rings. This molecular structure lacks classical hydrogen bonds and π-π interactions, offering insights into its chemical properties.

Area of Science:

Crystallography
Organic Chemistry
Molecular Structure

Background:

Understanding the three-dimensional arrangement of atoms in organic molecules is crucial for predicting their chemical behavior and physical properties.
Pyridine-containing compounds are prevalent in pharmaceuticals and materials science, necessitating detailed structural characterization.

Purpose of the Study:

To determine the precise molecular geometry and intermolecular interactions of the title compound, C(14)H(16)N(2).
To provide crystallographic data that can inform future research on related pyridine derivatives.

Main Methods:

Single-crystal X-ray diffraction was employed to analyze the crystal structure of C(14)H(16)N(2).
Analysis of the crystal structure involved determining atomic coordinates, bond lengths, bond angles, and dihedral angles.

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Main Results:

The title compound, C(14)H(16)N(2), exhibits no crystallographic molecular symmetry.
A dihedral angle of 19.48(2)° was measured between the least-squares planes of the two pyridine rings.
No classical hydrogen bonds or π-π interactions were identified in the crystal lattice.

Conclusions:

The determined dihedral angle provides specific geometric information about the relative orientation of the pyridine rings.
The absence of classical hydrogen bonds and π-π interactions suggests that other weaker forces may govern the crystal packing.
This structural data serves as a fundamental reference for C(14)H(16)N(2) and related molecular systems.