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Updated: Jun 5, 2026

Preparation of SNS Cobalt(II) Pincer Model Complexes of Liver Alcohol Dehydrogenase
Published on: March 19, 2020
Diaqua-bis(4-bromo-2-formyl-phenolato-κO,O')cobalt(II)
1The Guangxi Key Laboratory of Environmental Engineering, Protection and Assessment (Department of Resources and Environmental Engineering, Guilin University of Technology), Guilin 541004, People's Republic of China.
Abstract:
In the title complex, [Co(C(7)H(4)BrO(2))(2)(H(2)O)(2)], the Co(II) ion, which lies on a crystallographic inversion center, is coordin-ated by four O atoms from two bidentate 4-bromo-2-formyl-phenolate ligands and two O atoms from two water ligands in a slightly distorted octa-hedral environment. In the crystal structure, one-dimensional chains are formed through inter-molecular O-H⋯O hydrogen bonds, which are further linked into a two-dimensional network through Br⋯Br inter-actions [Br⋯Br = 3.772 (4) Å].
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