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Updated: Jun 5, 2026
Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)
Published on: November 22, 2016
[1,3-Bis(diphenyl-phosphino)propane-κP,P']diiodido(perfluoro-propyl)rhodium(III) dichloro-methane solvate
Basu Panthi1, Stephen L Gipson, Andreas Franken
1Chemistry Department, Baylor University, One Bear Place 97348, Waco, TX 76798, USA.
Abstract:
The structure of the title compound, [RhI(2)(C(3)F(7))(C(27)H(26)P(2))]·CH(2)Cl(2), at 110 (2) K is an unusual example of a structurally characterized square-based pyramidal alkyl complex of rhodium(III). The Rh-C bond is relatively short at 1.996 (6) Å. This short metal-carbon bond length is typical of perfluoro complexes of transition metals and illustrates the enhanced bond strength in these compounds.
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