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![[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Bis(acetato-κO)[N,N,N',N'-tetra-methyl-ethane-1,2-diamine-κN,N']copper(II)
1Laboratorium für Organische Chemie, Eidgenössische Technische Hochschule (ETH) Zürich, Wolfgang-Pauli-Strasse 10, 8093 Zürich, Switzerland.
Abstract:
In the title compound, [Cu(C(2)H(3)O(2))(2)(C(6)H(16)N(2))], the Cu(II) atom is coordinated by two N atoms from the chelating N,N,N',N'-tetra-methyl-ethane-1,2-diamine ligand and two O atoms from two acetate anions in a distorted square-planar geometry. In addition, there are longer contacts between Cu and the second O atom of each acetate ligand, which could be considered to complete a distorted octa-hedral geometry. The mol-ecules in the crystal structure are connected via inter-molecular C-H⋯O hydrogen-bonding contacts.
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