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Updated: Jun 5, 2026

Microwave-Assisted Preparation of 1-Aryl-1H-pyrazole-5-amines
Published on: June 23, 2019
4-(4-Bromo-phenyl-hydrazono)-1-(5-bromo-pyrimidin-2-yl)-3-methyl-2-pyrazolin-5-one
Abstract:
The asymmetric unit of the title compound, C(14)H(10)Br(2)N(6)O, contains two crystallographically independent mol-ecules. The pyrazole ring of one mol-ecule makes dihedral angles of 22.0 (3) and 3.5 (3)° with the pyrimidine and benzene rings, respectively; the corresponding values in the other mol-ecule are 9.2 (3) and 2.1 (3)°, respectively. The mol-ecules are linked by N-H⋯O, C-H⋯N and C-H⋯Br hydrogen bonds.
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