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Updated: Jun 5, 2026

Protocol for the Synthesis of Ortho-trifluoromethoxylated Aniline Derivatives
Published on: January 19, 2016
Benzoyl-methyl 4-chloro-benzoate
Yi Jin1, Jian-Nan Guo, Kan Lin
1Department of Chemistry, The Key Laboratory for Chemical Biology of Fujian Province, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, People's Republic of China.
Abstract:
The asymmetric unit of the title compound, C(15)H(11)ClO(3), contains three mol-ecules, A, B, and C. Mol-ecules A and B are aligned edge-to-face, whereas mol-ecules B and C are aligned almost parallel to each other. The crystal structure displays C-H⋯π and π-π [centroid-centroid distances of 3.960 (4), 3.971 (4) and 3.971 (4) for mol-ecules A, B and C, respectively] parallel-displaced inter-actions, and C-H⋯O hydrogen bonds.
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