trans-Aqua-(4,7-diaza-decane-1,10-diamine-κN)fluoridochromium(III) bis-(perchlorate) monohydrate
Acta Crystallographica. Section E, Structure Reports Online
|January 5, 2011
Abstract:
In the title compound, [CrF(C(8)H(20)N(4))(H(2)O)](ClO(4))(2)·H(2)O, the Cr atom is in a slightly distorted octa-hedral environment, coordinated by four N atoms of the 4,7-diaza-decane-1,10-diamine ligand, one water mol-ecule and an F atom trans to water. The five-membered chelate ring is in a gauche form, while the two six-membered chelate rings are in chair conformations. The crystal structure is stabilized by several hydrogen bonds.
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