![Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F51444.jpg&w=3840&q=50)
cis-Bis-[2-(diphenyl-phosphino)benzene-thiolato-κP,S]palladium(II)
Jaime Fierro-Arias1, David Morales-Morales, Simón Hernández-Ortega
1Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, México 04510, D. F., México .
Abstract:
The title compound, [Pd(C(18)H(14)PS)(2)], was synthesized by the reaction of (Ph(2)PC(6)H(4)SH) with [PdCl(2)(NCC(6)H(5))(2)] in a 2:1 molar ratio in the presence of a slight excess of NEt(3 )as base in dichloro-methane. The compound crystallizes with the Pd(II) atom on a twofold rotation axis. The palladium center has a slightly distorted square-planar environment, with the two P-S chelating ligands adopting a cis configuration. The present structure is a pseudo-polymorph of [Pd(C(18)H(14)PS)(2)]·CH(2)Cl(2).
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