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Updated: Jun 5, 2026

Synthesis of Triazole and Tetrazole-Functionalized Zr-Based Metal-Organic Frameworks Through Post-Synthetic Ligand Exchange
Published on: June 23, 2023
2,4,6-Triamino-1,3,5-triazine-1,3-diium aqua-penta-fluoridoaluminate
A Cadiau1, A Hemon-Ribaud, M Leblanc
1Laboratoire des Oxydes et Fluorures - UMR 6010 CNRS, Faculté des Sciences et Techniques, Université du Maine, Avenue Olivier Messiaen, 72085 Le Mans Cedex 9, France.
Abstract:
The title compound, (C(3)H(8)N(6))[AlF(5)(H(2)O)], was obtained by solvothermal synthesis from the reaction of aluminium hydroxide, 1,3,5-triazine-2,4,6-triamine (melamine), aqueous HF and water at 323 K for 48 h. The structure consists of [AlF(5)(H(2)O)](2-) octa-hedra and diprotonated melaminium cations. Cohesion is ensured by a three-dimensional network of hydrogen bonds.
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