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Related Concept Videos

Upper GI Series: Barium Swallow01:24

Upper GI Series: Barium Swallow

The Barium Swallow Study, or a Barium Esophagogram, is a diagnostic imaging method used to visualize the upper gastrointestinal (GI) tract, including the esophagus, stomach, and small intestine. It employs barium sulfate, a radiopaque contrast material, to provide clear images of the upper digestive system, helping to identify abnormalities, diseases, or structural issues.
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Patients undergoing this procedure ingest a liquid containing barium sulfate with a chalky...
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Qualitative Analysis

For solutions containing mixtures of different cations, the identity of each cation can be determined by qualitative analysis. This technique involves a series of selective precipitations with different chemical reagents, each reaction producing a characteristic precipitate for a specific group of cations. Metal ions within a group are further separated by varying the pH, heating the mixture to redissolve a precipitate, or adding other reagents to form complex ions.
For instance, group IV...
Ionic Compounds: Formulas and Nomenclature03:34

Ionic Compounds: Formulas and Nomenclature

An element composed of atoms that readily lose electrons (a metal) can react with an element composed of atoms that readily gain electrons (a nonmetal) to produce ions through complete electron transfer. The compound formed by this transfer is stabilized by the electrostatic attractions (ionic bonds) between the oppositely charged ions.
Valence Bond Theory02:42

Valence Bond Theory

Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
Lower GI Series: Barium Enema01:23

Lower GI Series: Barium Enema

A Barium Enema, or a lower GI series, is a specialized radiographic examination designed to visualize the lower gastrointestinal tract, specifically the colon and rectum. This procedure is instrumental in diagnosing various conditions such as colorectal cancer, polyps, diverticulosis, and inflammatory bowel disease.
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Titration of Polyprotic Base with a Strong Acid

The titration of a polyprotic base such as sodium carbonate with a strong acid such as hydrochloric acid results in two equivalence points on the titration curve. At the first equivalence point, the carbonate ions in the base are completely converted to bicarbonate ions. The second equivalence point corresponds to the complete conversion of bicarbonate ions to carbonic acid, which dissociates into carbon dioxide and water. The region before the first equivalence point corresponds to the...

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Related Experiment Video

Updated: Jun 5, 2026

Chemical Synthesis of Porous Barium Titanate Thin Film and Thermal Stabilization of Ferroelectric Phase by Porosity-Induced Strain
08:00

Chemical Synthesis of Porous Barium Titanate Thin Film and Thermal Stabilization of Ferroelectric Phase by Porosity-Induced Strain

Published on: March 27, 2018

Poly[[μ(2)-aqua-aqua-(μ(3)-3,5-dinitro-salicylato)barium(II)] monohydrate].

Wen-Dong Song1, Run-Zhen Fan, Chang-Sheng Gu

  • 1College of Science, Guang Dong Ocean University, Zhanjiang 524088, People's Republic of China.

Acta Crystallographica. Section E, Structure Reports Online
|January 5, 2011
PubMed
Summary

This study details a new coordination polymer, {[Ba(C(7)H(2)N(2)O(7))(H(2)O)(2)]·H(2)O}(n), featuring barium ions linked by dinitrosalicylate ligands. These units form infinite chains and a supramolecular network via hydrogen bonding.

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Last Updated: Jun 5, 2026

Chemical Synthesis of Porous Barium Titanate Thin Film and Thermal Stabilization of Ferroelectric Phase by Porosity-Induced Strain
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Controlling the Size, Shape and Stability of Supramolecular Polymers in Water
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Investigations on the Ga(III) Complex of EOB-DTPA and Its 68Ga Radiolabeled Analogue
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Investigations on the Ga(III) Complex of EOB-DTPA and Its 68Ga Radiolabeled Analogue

Published on: August 17, 2016

Area of Science:

  • Inorganic Chemistry
  • Crystallography
  • Materials Science

Background:

  • Coordination polymers offer tunable properties for diverse applications.
  • Barium-based coordination polymers are less explored than those of other alkaline earth metals.

Purpose of the Study:

  • To synthesize and characterize a novel barium coordination polymer using 3,5-dinitrosalicylate ligands.
  • To investigate the structural features and supramolecular assembly of the resulting material.

Main Methods:

  • Single-crystal X-ray diffraction was employed to determine the precise atomic arrangement.
  • Infrared spectroscopy and thermal analysis were used for further characterization.

Main Results:

  • A novel coordination polymer, {[Ba(C(7)H(2)N(2)O(7))(H(2)O)(2)]·H(2)O}(n), was successfully synthesized.
  • The barium(II) center exhibits ten-coordination with a bicapped square-antiprismatic geometry.
  • 3,5-dinitrosalicylate ligands bridge three barium atoms, forming dinuclear barium units.
  • These units assemble into infinite chains and a supramolecular network via hydrogen bonding.

Conclusions:

  • The study presents a new barium coordination polymer with a unique structural motif.
  • Hydrogen bonding plays a crucial role in the formation of the extended supramolecular network.