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Updated: Jun 5, 2026

Preparation of Contiguous Bisaziridines for Regioselective Ring-Opening Reactions
Published on: July 28, 2022
2,2'-(Imino-dimethyl-ene)dibenz-imid-azol-ium bis-(perchlorate) methanol solvate
Chun-Shan Zhou1, Xue-Ying Huang, Xiang-Gao Meng
1Key Laboratory of Pesticides and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, People's Republic of China.
Abstract:
In the title compound, C(16)H(17)N(5) (2+)·2ClO(4) (-)·CH(3)OH, the dihedral angle between the two benzimidazolium ring systems is 34.6 (1)°. The anions and solvent mol-ecules are linked to the cation by N-H⋯O hydrogen bonds. In the crystal structure, the combination of N-H⋯O and O-H⋯O hydrogen bonds results in two-dimensional layers running parallel to the (010) plane; these are in turn linked by π-π inter-actions, forming a three-dimensional network.
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