Jove
Visualize
Contact Us

Related Concept Videos

Ionic Crystal Structures02:42

Ionic Crystal Structures

Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Crystal Field Theory - Octahedral Complexes02:58

Crystal Field Theory - Octahedral Complexes

Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
Colors and Magnetism03:02

Colors and Magnetism

Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human eye.
Valence Bond Theory02:42

Valence Bond Theory

Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
Experimental Determination of Chemical Formula02:37

Experimental Determination of Chemical Formula

The elemental makeup of a compound defines its chemical identity, and chemical formulas are the most concise way of representing this elemental makeup. When a compound’s formula is unknown, measuring the mass of its constituent elements is often the first step in determining the formula experimentally.
Properties of Organometallic Compounds01:23

Properties of Organometallic Compounds

Organometallic compounds are compounds that contain a carbon–metal bond. Carbon belongs to an organyl group like alkyl, aryl, allyl, or benzyl groups. The metal can be from Group I or Group II of the periodic table, a transition metal, or a semimetal.

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

A disorder-enhanced quasi-one-dimensional superconductor.

Nature communications·2016
Same author

Na4.25Mo15S19: a novel ternary reduced molybdenum sulfide containing Mo6 and Mo9 clusters.

Acta crystallographica. Section E, Structure reports online·2014
Same author

Multiband superconductivity in the Chevrel phases SnMo6S8 and PbMo6S8.

Physical review letters·2011
Same author

Ag(2.54)Tl(2)Mo(12)Se(15): a new structure type containing Mo(6) and Mo(9) clusters.

Acta crystallographica. Section C, Crystal structure communications·2010
Same author

Real-space vortex glass imaging and the vortex phase diagram of SnMo6S8.

Physical review letters·2010
Same author

Synthesis, crystal structures, and physical properties of the novel Ca(x)R(17-x)Mo19O46 (4 < or = x < or = 7; R = Ce, Pr, Sm, and Gd) compounds containing centered Mo19 nu2-octahedral clusters.

Inorganic chemistry·2010
Same journal

Crystal structure of 1-(piperidin-1-yl)butane-1,3-dione.

Acta crystallographica. Section E, Structure reports online·2015
Same journal

Crystal structure of methyl 1-methyl-3,5-diphenyl-7-tosyl-3,6,7,11b-tetra-hydro-pyrazolo-[4',3':5,6]pyrano[3,4-c]quinoline-5a(5H)-carboxyl-ate.

Acta crystallographica. Section E, Structure reports online·2015
Same journal

Crystal structure of 4-amino-1-(4-methyl-benz-yl)pyridinium bromide.

Acta crystallographica. Section E, Structure reports online·2015
Same journal

Crystal structure of (Z)-3-benz-yloxy-6-[(2-hy-droxy-anilino)methyl-idene]cyclo-hexa-2,4-dien-1-one.

Acta crystallographica. Section E, Structure reports online·2015
Same journal

Crystal structure of bis-(1-benzyl-1H-1,2,4-triazole) perchloric acid monosolvate.

Acta crystallographica. Section E, Structure reports online·2015
Same journal

Crystal structure of 2-(di-phenyl-phos-phanyl)phenyl 4-(hy-droxy-meth-yl)benzoate.

Acta crystallographica. Section E, Structure reports online·2015
See all related articles
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Video

Updated: Jun 5, 2026

Molten-Salt Synthesis of Complex Metal Oxide Nanoparticles
08:43

Molten-Salt Synthesis of Complex Metal Oxide Nanoparticles

Published on: October 27, 2018

The pyrochlore-type molybdate Pr(1.37)Ca(0.63)Mo(2)O(7).

P Gall1, P Gougeon

  • 1Unité Sciences Chimiques de Rennes, UMR CNRS No. 6226, Université de Rennes I-INSA Rennes, Campus de Beaulieu, 35042 Rennes CEDEX, France.

Acta Crystallographica. Section E, Structure Reports Online
|January 5, 2011
PubMed
Summary
This summary is machine-generated.

Praseodymium calcium dimolybdenum hepta-oxide forms a cubic pyrochlore-type structure. This study details its crystal structure, revealing linked MoO(6) octahedra and statistically distributed Pr and Ca atoms within the voids.

More Related Videos

High Pressure Single Crystal Diffraction at PX^2
11:32

High Pressure Single Crystal Diffraction at PX^2

Published on: January 16, 2017

Quantitative Atomic-Site Analysis of Functional Dopants/Point Defects in Crystalline Materials by Electron-Channeling-Enhanced Microanalysis
07:24

Quantitative Atomic-Site Analysis of Functional Dopants/Point Defects in Crystalline Materials by Electron-Channeling-Enhanced Microanalysis

Published on: May 10, 2021

Related Experiment Videos

Last Updated: Jun 5, 2026

Molten-Salt Synthesis of Complex Metal Oxide Nanoparticles
08:43

Molten-Salt Synthesis of Complex Metal Oxide Nanoparticles

Published on: October 27, 2018

High Pressure Single Crystal Diffraction at PX^2
11:32

High Pressure Single Crystal Diffraction at PX^2

Published on: January 16, 2017

Quantitative Atomic-Site Analysis of Functional Dopants/Point Defects in Crystalline Materials by Electron-Channeling-Enhanced Microanalysis
07:24

Quantitative Atomic-Site Analysis of Functional Dopants/Point Defects in Crystalline Materials by Electron-Channeling-Enhanced Microanalysis

Published on: May 10, 2021

Area of Science:

  • Solid-state chemistry
  • Crystallography
  • Materials science

Background:

  • The pyrochlore structure type is a versatile framework for complex oxides.
  • Understanding the atomic arrangement in novel oxide compounds is crucial for predicting their properties.

Purpose of the Study:

  • To elucidate the crystal structure of Praseodymium calcium dimolybdenum hepta-oxide, Pr(1.37)Ca(0.63)Mo(2)O(7).
  • To characterize the coordination and site occupancy of Pr, Ca, Mo, and O atoms within the pyrochlore lattice.

Main Methods:

  • Single-crystal X-ray diffraction was employed to determine the crystal structure.
  • Rietveld refinement was used to analyze atomic positions and site occupancies.

Main Results:

  • The compound crystallizes in the cubic pyrochlore-type structure.
  • Molybdenum atoms form a 3D [Mo(2)O(6)] network of corner-sharing MoO(6) octahedra.
  • Pr and Ca atoms are statistically distributed over the 16c crystallographic position within the network voids, coordinated by eight oxygen atoms.

Conclusions:

  • The detailed crystal structure of Pr(1.37)Ca(0.63)Mo(2)O(7) has been determined.
  • The arrangement of atoms and the formation of the [Mo(2)O(6)] network are key features of this pyrochlore compound.