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Updated: Jun 5, 2026
09:35
Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
Published on: September 18, 2016
catena-Poly[[aqua-glycolatocopper(II)]-μ-chlorido]
Acta Crystallographica. Section E, Structure Reports Online
|January 5, 2011
Summary
This study reveals a novel 3D network structure of copper(II) glycolate chains linked by hydrogen bonds. The crystal structure features distorted square-pyramidal copper(II) ions forming one-dimensional chains.
Area of Science:
- Inorganic Chemistry
- Crystallography
- Materials Science
Background:
- Copper(II) complexes are known for diverse structural motifs.
- Glycolate ligands can form chelating coordination modes.
- Understanding crystal packing is crucial for materials properties.
Purpose of the Study:
- To determine the crystal structure of the title compound, [Cu(C(2)H(3)O(3))Cl(H(2)O)](n).
- To elucidate the coordination geometry and intermolecular interactions.
- To describe the formation of a three-dimensional polymeric network.
Main Methods:
- Single-crystal X-ray diffraction analysis.
- Determination of atomic coordinates and bond lengths.
- Analysis of coordination geometry and hydrogen bonding.
Main Results:
- The copper(II) ion exhibits a five-coordinate, distorted square-pyramidal geometry.
- Chelating glycolate anions, water molecules, and chloride ions form the coordination sphere.
- Chloride bridges link copper units into 1D chains, further connected into a 3D network via hydrogen bonds.
Conclusions:
- The crystal structure reveals a unique 3D polymeric network built from 1D copper(II) glycolate chains.
- Hydrogen bonding plays a critical role in stabilizing the extended network structure.
- The study provides insights into the supramolecular assembly of copper coordination compounds.
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