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Updated: Jun 5, 2026

Synthesis of a Water-soluble Metal–Organic Complex Array
Published on: October 8, 2016
catena-Poly[[bis-(methanol-κO)bis-(pyridine-κN)nickel(II)]-μ-tetra-fluoro-terephthalato-κO:O']
Chang-Ge Zheng1, Jian-Quan Hong, Jie Zhang
1School of Chemical and Materials Engineering, Jiangnan University, 1800 Lihu Road, Wuxi, Jiangsu Province 214122, People's Republic of China.
Abstract:
In the title compound, [Ni(C(8)F(4)O(4))(C(5)H(5)N)(2)(CH(4)O)(2)](n), the Ni(II) ion is located on an inversion center and is coordinated by four O atoms [Ni-O = 2.079 (4) Å] from two tetra-fluoro-terephthalate ligands and two methanol mol-ecules, and by two N atoms [Ni-N = 2.127 (4) Å] from two pyridine ligands in a distorted octa-hedral geometry. The Ni(II) ions are connected via the tetra-fluoro-terephthalate anions into a one-dimensional chain running along the crystallographic [011] direction.
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