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Updated: Jun 5, 2026

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Benzamidinium tetra-hydro-penta-borate sesquihydrate
1Chemistry Department, University of Rome "La Sapienza", P.le A. Moro 5, I-00185 Rome, Italy.
Abstract:
THE ASYMMETRIC UNIT OF THE TITLE COMPOUND [SYSTEMATIC NAME: benzamidinium 3,3',5,5'-tetra-hydr-oxy-1,1'-spirobi[2,4,6-trioxa-1,3,5-triboracyclo-hexa-ne](1-) sesquihydrate], C(7)H(9)N(2) (+)·B(5)H(4)O(10) (-)·1.5H(2)O, is composed of two protonated benzamidinium cations, two tetra-hydro-penta-borate anions and three water mol-ecules of crystallization. The ions and water molecules are associated in the crystal structure by an extensive three-dimensional hydrogen-bonding network, which consists mainly of cation-to-anion N-H⋯O and anion-to-anion O-H⋯O hydrogen bonds.
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