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Updated: Jun 5, 2026

Synthesis of a Water-soluble Metal–Organic Complex Array
Published on: October 8, 2016
catena-Poly[[chloridocobalt(II)]-μ-5-(8-quinolyloxymeth-yl)tetra-zolato-κN,O,N:N]
1Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, People's Republic of China.
Abstract:
In the title compound, [Co(C(11)H(8)N(5)O)Cl](n), the Co(II) atom is penta-coordinated by one O atom and two N atoms from a 5-(8-quinolyloxymeth-yl)tetra-zolate ligand, one N atom from another symmetry-related ligand, and a Cl atom. The coordination geometry can be described as slightly distorted trigonal-bipyramidal. Adjacent Co atoms are connected by the bridging tetra-zole groups into a chain. The dihedral angle between the quinoline and tetra-zole planes is 21.2 (1)°. The structure involves intra- and inter-chain C-H⋯N hydrogen bonds.
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