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Updated: Jun 5, 2026

Manganese Oxide Nanoparticle Synthesis by Thermal Decomposition of Manganese(II) Acetylacetonate
Published on: June 18, 2020
Poly[[aqua-[μ(3)-(2,6-H(2))-isonicotinato-κN:O:O'][μ(2)-(2,6-H(2))-isonicotinato-κN:O]manganese(II)] ethanol solvate]
1Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, People's Republic of China.
Abstract:
In the title compound, {[Mn(C(6)H(2)D(2)NO(2))(2)(H(2)O)]·C(2)H(6)O}(n), the Mn(II) metal centre displays a slightly distorted octa-hedral coordination geometry, provided by three O and two N atoms of five isonicotinate ligands and one O atom of a water mol-ecule. There are two types of isonicotinate anions, one acting as a bridging tridentate group and the other in a bridging bidentate fashion, to form a polymeric three-dimensional network. The structure is stabilized by intra- and inter-molecular O-H⋯O and C-H⋯O hydrogen-bond inter-actions.
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