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Updated: Jun 5, 2026
A Technical Guide for Performing Spectroscopic Measurements on Metal-Organic Frameworks
Published on: April 28, 2023
Synthesis, structure and photophysical properties of two transitional metal supramolecular complexes
Cai Shun Zhang1, Jing Li, Ke Ling Hou
1College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, PR China.
Abstract:
Two supramolecular complexes: [Co(2,6-PDC)(Hdmpz)3]·H2O (1) and [Zn(2,6-PDC)(Hdmpz)2] (2) {2,6-PDC=pyridine-2,6-dicarboxylic acid, Hdmpz=3,5-dimethylpyrazol}, self-assembles via O-H⋯O and N-H⋯O hydrogen bondings into supramolecular networks, which are characterized by elemental analyses, IR spectra and single crystal X-ray diffraction analysis. Both of them consist of two-dimensional networks that are stacked together by typical hydrogen bonding interactions (i.e. O-H⋯O and N-H⋯O), which often play important roles in the formation of low-dimensional into high-dimensional supramolecular networks. In addition, quantum chemistry calculations and surface photovoltage spectroscopy are performed firstly with the complexes.
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