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Charm-bracelet-type poly(N-vinylcarbazole) functionalized with reduced graphene oxide for broadband optical limiting

Pei-Pei Li1, Yu Chen, Jinhui Zhu

  • 1Key Laboratory for Advanced Materials, Institute of Applied Chemistry, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, PR China.

Chemistry (Weinheim an Der Bergstrasse, Germany)
|January 13, 2011
PubMed
Abstract

No abstract available in PubMed .

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Ring-opening metathesis polymerization or ROMP involves strained cycloalkenes as starting materials. The mechanism of ROMP proceeds by reacting cycloalkene with Grubbs catalyst to give metallacyclobutane intermediate which undergoes a ring-opening reaction to form new carbene. The new carbene reacts with another molecule of cycloalkene. Repetition of these steps leads to the formation of an unsaturated open-chain polymer product. All these steps are reversible, however, relieving the ring...

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