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Updated: Jun 5, 2026

Cooling Rate Dependent Ellipsometry Measurements to Determine the Dynamics of Thin Glassy Films
Published on: January 26, 2016
Evidence for critical-like behavior in ultraslowing glass-forming systems
Aleksandra Drozd-Rzoska1, Sylwester J Rzoska, Sebastian Pawlus
1Institute of High Pressure Physics, Polish Academy of Sciences, ul. Sokołowska 27/39, 01-143 Warsaw, Poland.
Abstract:
Glass transition constitutes one of main problems of condensed matter physics and material engineering that remains unsolved. The common acceptance of the Vogel-Fulcher-Tammann (VFT) equation for portraying the primary relaxation time or shear viscosity indicated a possible phase transition, hidden below the glass transition temperature (T(g)). Recently Hecksher [Nat. Phys. 4, 737 (2008)] delivered strong empirical arguments that VFT description lacks a direct experimental basis and thus theories not predicting a dynamic divergence should be focused on. We present clear evidence for a superiority of critical-like divergent equation τ(T)=τ(0)(T-T(C))(-ϕ) and T(C)

