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Updated: Jun 5, 2026

Controlling the Size, Shape and Stability of Supramolecular Polymers in Water
Published on: August 2, 2012
Effect of polydispersity on the ordering transition of adsorbed self-assembled rigid rods
N G Almarza1, J M Tavares, M M Telo da Gama
1Instituto de Química Física Rocasolano, CSIC, Serrano 119, E-28006 Madrid, Spain.
Abstract:
Extensive Monte Carlo simulations were carried out to investigate the nature of the ordering transition of a model of adsorbed self-assembled rigid rods on the bonds of a square lattice [Tavares, Phys. Rev. E 79, 021505 (2009)]. The polydisperse rods undergo a continuous ordering transition that is found to be in the two-dimensional Ising universality class, as in models where the rods are monodisperse. This finding is in sharp contrast with the recent claim that equilibrium polydispersity changes the nature of the phase transition in this class of models [López, Phys. Rev. E 80, 040105(R) (2009)].
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