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Collective shape oscillations of SiGe islands on pit-patterned Si(001) substrates: a coherent-growth strategy enabled

J J Zhang1, F Montalenti, A Rastelli

  • 1Institut für Halbleiter-und Festkörperphysik, Universität Linz, A-4040 Linz, Austria. j.zhang@ifw-dresden.de

Physical Review Letters
|January 15, 2011
PubMed

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Sigmatropic rearrangements are a class of pericyclic reactions in which a σ bond migrates from one part of a π system to another. These are intramolecular rearrangements where the total number of σ and π bonds remain unchanged.
Sigmatropic shifts are classified based on an order term [i, j ], where i and j indicate the number of atoms across which each end of the σ bond migrates. Below are examples of a [3,3] sigmatropic shift in 1,5-hexadiene, referred to as...