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Archimedes-Based Glycerol Displacement for Electrode Porosity Measurement in Lead-Acid Batteries
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Published on: April 7, 2026

Relativity and the lead-acid battery.

Rajeev Ahuja1, Andreas Blomqvist, Peter Larsson

  • 1Division of Materials Theory, Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20, Uppsala, Sweden. rajeev.ahuja@fysik.uu.se

Physical Review Letters
|January 15, 2011
PubMed
Summary

This study calculates lead-acid battery reactant energies using ab initio methods. Relativistic effects significantly contribute 1.7-1.8 V to the standard voltage, closely matching experimental values.

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Area of Science:

  • Computational chemistry
  • Electrochemistry

Background:

  • Lead-acid batteries are crucial energy storage devices.
  • Accurate theoretical prediction of battery performance is essential for development.

Purpose of the Study:

  • To calculate the energies of solid reactants in lead-acid batteries.
  • To investigate the contribution of relativistic effects to the standard voltage.

Main Methods:

  • Ab initio calculations using two basis sets.
  • Nonrelativistic, scalar-relativistic, and fully relativistic levels.
  • Multiple exchange-correlation potentials were employed.

Main Results:

  • The average calculated standard voltage is 2.13 V, closely matching the experimental value of 2.11 V.
  • Relativistic effects account for 1.7-1.8 V of the standard voltage.
  • Relativistic effects are significant in both PbO2 and PbSO4.

Conclusions:

  • Ab initio calculations accurately predict lead-acid battery standard voltage.
  • Relativistic effects play a dominant role in determining the battery's voltage.
  • Theoretical methods can reliably model electrochemical systems.