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Updated: Jun 5, 2026

Tuning the Acidity of Pt/ CNTs Catalysts for Hydrodeoxygenation of Diphenyl Ether
Published on: August 17, 2019
Liquid phase hydrodechlorination of chlorophenols at lower temperature on a novel Pd catalyst
Zhonghao Jin1, Chao Yu, Xingyi Wang
1Laboratory for Advanced Materials, Research Institute of Industrial Catalysis, East China University of Science and Technology, Shanghai 200237, China.
Abstract:
Pd catalyst supported on mesoporous silica-carbon nano-composite (Pd/MSCN) was prepared by the method of wet impregnation, and its activity for hydrodechlorination (HDC) of 2-chlorophenol, 4-chlorophenol and 2,4-dichlorophenol was evaluated at 258-313 K under ordinary hydrogen pressure by using triethylamine (Et(3)N) as a base additive. XRD analysis indicates that Pd/MSCN catalyst possesses the ordered mesostructure. Meanwhile, the results from TEM and H(2) chemisorption analysis indicate the high dispersion of Pd on MSCN with Pd nanoparticles whose average size is 3.2 nm. For the first time, the high activity of nano-size Pd on MSCN for HDC of chlorophenols was observed at 258 K. In addition, it was found that the inhibition effect of Et(3)N on HDC existed obviously, and can be efficiently reduced by stepwise addition of Et(3)N. The correlations of the dielectric constants of base and the polarity of solvent to the activity of Pd/MSCN for HDC of chlorophenols were obtained.
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