Related Experiment Video
Updated: Jun 5, 2026

Reductive Electropolymerization of a Vinyl-containing Poly-pyridyl Complex on Glassy Carbon and Fluorine-doped Tin Oxide Electrodes
Published on: January 30, 2015
Vinylarene/CO copolymerization and vinylarene/polar vinyl monomer/CO terpolymerization using
Takeharu Kageyama1, Shingo Ito, Kyoko Nozaki
1Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.
Abstract:
Palladium/phosphine-sulfonate complexes were effective for the alternating copolymerization of vinylarenes with carbon monoxide (CO). The obtained copolymers had iso-enriched microstructures with ll selectivity of up to circa 60%. The catalytic system was successfully applied to the terpolymerization of vinylarene and polar vinyl monomers with CO to produce novel terpolymers, which could not be obtained by using previously developed catalysts. NMR and DSC analyses suggested that vinylarene/CO units and polar vinyl monomer/CO units were randomly distributed in the terpolymer main chains.
More Related Videos
11:44Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
Published on: March 20, 2014
06:49Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst
Published on: April 22, 2016
Related Concept Videos
Olefin Metathesis Polymerization: Ring-Opening Metathesis Polymerization (ROMP)
Olefin Metathesis Polymerization: Overview
Ruthenium-based Grubbs catalyst is the most commonly used catalyst for olefin metathesis polymerization. Grubbs catalyst consists of a...
Cationic Chain-Growth Polymerization: Mechanism
Anionic Chain-Growth Polymerization: Mechanism
Anionic Chain-Growth Polymerization: Overview
Ziegler–Natta Chain-Growth Polymerization: Overview