Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Atomic Emission Spectroscopy: Interference01:30

Atomic Emission Spectroscopy: Interference

In atomic emission spectroscopy (AES), high-temperature atomizers excite a broad range of elements and molecules that generate complex emissions from sources such as oxides, hydroxides, and flame combustion products in the flame or plasma. Several strategies can be employed to minimize spectral interferences caused by overlapping emission lines or bands. These include increasing instrument resolution, choosing alternative emission lines, optimally placing the detector in low-background regions,...
Hybridization of Atomic Orbitals II03:35

Hybridization of Atomic Orbitals II

sp3d and sp3d 2 Hybridization
¹H NMR: Long-Range Coupling01:27

¹H NMR: Long-Range Coupling

The coupling interactions of nuclei across four or more bonds are usually weak, with J values less than 1 Hz. While these are usually not observed in spectra, the presence of multiple bonds along the coupling pathway can result in observable long-range coupling.
In alkenes, spin information is communicated via σ–π overlap, as seen in allylic (four-bond) and homoallylic (five-bond) couplings. These coupling interactions are stronger when the σ bond is parallel to the alkene π orbitals.
Hybridization of Atomic Orbitals I03:24

Hybridization of Atomic Orbitals I

The mathematical expression known as the wave function, ψ, contains information about each orbital and the wavelike properties of electrons in an isolated atom. When atoms are bound together in a molecule, the wave functions combine to produce new mathematical descriptions that have different shapes. This process of combining the wave functions for atomic orbitals is called hybridization and is mathematically accomplished by the linear combination of atomic orbitals. The new orbitals that...
Atomic Absorption Spectroscopy: Interference01:25

Atomic Absorption Spectroscopy: Interference

Interference leads to systematic error in atomic absorption (AA) measurements by enhancing or diminishing the analytical signal or the background. These interferences can be grouped into three main categories: spectral interference, chemical interference, and physical interference.
Spectral interference occurs when signals from other elements or molecules overlap with the analyte signal, falsely elevating or masking the analyte's absorbance. This interference can be corrected using Zeeman,...
Double Resonance Techniques: Overview01:12

Double Resonance Techniques: Overview

Double resonance techniques in Nuclear Magnetic Resonance (NMR) spectroscopy involve the simultaneous application of two different frequencies or radiofrequency pulses to manipulate and observe two distinct nuclear spins. One important application of double resonance is spin decoupling, which selectively suppresses coupling with one type of nucleus while observing the NMR signal from another nucleus, simplifying the spectrum and enhancing resolution.
Spin decoupling is usually achieved by...

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

[Multispectral remote sensing image denoising based on non-local means].

Guang pu xue yu guang pu fen xi = Guang pu·2012
Same author

BAG3: a new therapeutic target of human cancers?

Histology and histopathology·2012
Same author

Z-Selectivity in olefin metathesis with chelated Ru catalysts: computational studies of mechanism and selectivity.

Journal of the American Chemical Society·2012
Same author

Complications after pancreaticoduodenectomy for pancreatic cancer: a retrospective study.

International surgery·2012
Same author

[Inhibitory effect of valproic acid on xenografted Kasumi-1 tumor growth in nude mouse and its mechanism].

Zhonghua xue ye xue za zhi = Zhonghua xueyexue zazhi·2012
Same author

[Foix syndrome secondary to chemotherapy of acute nonlymphocytic leukemia: a case report and review of the literature].

Zhonghua xue ye xue za zhi = Zhonghua xueyexue zazhi·2012

Related Experiment Video

Updated: Jun 5, 2026

Direct Imaging of Laser-driven Ultrafast Molecular Rotation
10:52

Direct Imaging of Laser-driven Ultrafast Molecular Rotation

Published on: February 4, 2017

Two-center interference during the high harmonic generation in aligned O2 molecules.

Pengfei Wei1, Yongli Yu, Xiaodong Guo

  • 1College of Physics & Electronic Information Engineering, Wenzhou University, Wenzhou, China.

Optics Express
|January 26, 2011
PubMed
Summary

We studied two-center interference in high-order harmonic generation (HHG) from O2 and CO2 molecules. We found that laser intensity can shift the constructive enhancement spectral region in O2 molecules.

More Related Videos

Measurement of Ultrafast Vibrational Coherences in Polyatomic Radical Cations with Strong-Field Adiabatic Ionization
08:22

Measurement of Ultrafast Vibrational Coherences in Polyatomic Radical Cations with Strong-Field Adiabatic Ionization

Published on: August 6, 2018

Related Experiment Videos

Last Updated: Jun 5, 2026

Direct Imaging of Laser-driven Ultrafast Molecular Rotation
10:52

Direct Imaging of Laser-driven Ultrafast Molecular Rotation

Published on: February 4, 2017

Measurement of Ultrafast Vibrational Coherences in Polyatomic Radical Cations with Strong-Field Adiabatic Ionization
08:22

Measurement of Ultrafast Vibrational Coherences in Polyatomic Radical Cations with Strong-Field Adiabatic Ionization

Published on: August 6, 2018

Area of Science:

  • Atomic, Molecular, and Optical Physics
  • Quantum Optics
  • Laser Physics

Background:

  • High-order harmonic generation (HHG) is a crucial nonlinear process for producing coherent extreme ultraviolet and X-ray radiation.
  • Molecular HHG exhibits complex interference patterns influenced by molecular structure and laser parameters.
  • Understanding two-center interference is key to controlling HHG spectra for applications.

Purpose of the Study:

  • To experimentally investigate the angular distribution and laser intensity dependence of two-center interference in O2 molecules.
  • To compare the HHG dynamics of O2 with CO2 molecules.
  • To explore the tunability of constructive enhancement in O2 HHG by varying laser intensity.

Main Methods:

  • Experimental measurement of high-order harmonic generation (HHG) from O2 and CO2 molecules.
  • Analysis of the temporal evolution and angular distribution of HHG signals.
  • Application of a modified interference model to explain observed phenomena.

Main Results:

  • Observed characteristic enhancement and suppression in HHG from O2 molecules, consistent with the modified interference model.
  • Demonstrated that the spectral region of constructive enhancement in aligned O2 molecules is tunable.
  • Showed that tuning the driving laser intensity shifts the constructive enhancement spectral region.

Conclusions:

  • The modified interference model accurately explains the observed two-center interference in O2 and CO2 HHG.
  • Laser intensity provides a controllable parameter to tune the spectral features of molecular HHG.
  • This work offers insights into controlling molecular HHG for potential applications in attosecond science and spectroscopy.