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Related Experiment Video

Updated: Jun 5, 2026

Triplet Fusion Upconversion Nanocapsule Synthesis
08:36

Triplet Fusion Upconversion Nanocapsule Synthesis

Published on: September 7, 2022

Highly efficient multiphoton-absorbing quadrupolar oligomers for frequency upconversion.

Xin Jiang Feng1, Po Lam Wu, King Fai Li

  • 1Department of Chemistry and Centre for Advanced Luminescence Materials, Hong Kong Baptist University, Kowloon Tong, Hong Kong SAR, P. R. China.

Chemistry (Weinheim an Der Bergstrasse, Germany)
|January 26, 2011
PubMed
Summary

New quadrupolar oligofluorenes with D-π-D and D-π-A-π-D structures show strong multiphoton absorption. The D-π-D molecules exhibit superior frequency-upconverted deep blue lasing, offering insights for designing efficient photoluminescent and lasing materials.

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Area of Science:

  • Organic Chemistry
  • Materials Science
  • Photophysics

Background:

  • Oligofluorenes are explored for optoelectronic applications.
  • Diphenylamino-endcapped oligofluorenes with D-π-D and D-π-A-π-D motifs were synthesized.
  • The study investigates multiphoton absorption and emission properties.

Purpose of the Study:

  • To synthesize and characterize novel quadrupolar oligofluorenes.
  • To evaluate their multiphoton absorption and photoluminescence.
  • To investigate their suitability for frequency-upconverted lasing applications.

Main Methods:

  • Palladium-catalyzed Suzuki cross-coupling for synthesis.
  • Infrared femtosecond laser pumping for excitation.
  • Spectroscopic analysis of photoluminescence and lasing properties.

Main Results:

  • Synthesized two series of quadrupolar oligofluorenes: PhN-OF(n)-NPh and PhN-OF(n)-TAZ-OF(n)-NPh.
  • Observed strong multiphoton-excited blue photoluminescence.
  • Achieved high three-photon absorption cross-sections (up to 2.72×10(-77) cm(6) s(2)).
  • PhN-OF(n)-NPh oligomers demonstrated intense, efficient multiphoton-excited frequency-upconverted deep blue lasing with record efficiency (0.097%).

Conclusions:

  • Quadrupolar molecules are superior to dipolar counterparts for multiphoton excited frequency-upconverted lasing.
  • The D-π-D oligofluorenes show remarkable lasing performance.
  • Findings provide guidelines for designing efficient three-photon absorption molecules for photoluminescence and lasing.